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ReRAM Startup Bets on Silver

8/5/2013 11:02 AM EDT
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Ron Neale
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Re: CBRAM? ECM or EM good question
Ron Neale   10/1/2013 2:59:10 PM
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Resistion-I went back and had a look at K-H Kim's thesis. It states "..movement of Ag ions in the a-Si matrix..." Suggesting a belief that those were ions moving towards the cathode, with a positive charge. Belief because there was not much evidence provided to prove the point; perhaps I missed it. It is not clear to me what elements provide for the oxidation-reduction prcess to form a ECM cell and provide the positive charged ions that you suggested need to be neutralized. Describe that for me with the elements available and you can have your positively charged Ag ion.

The thesis also states ".. Current can only flow through the device with a positve bias.." By that I think it is the current for programming to the low resistance state making the Ag electrode positive. The reason for that is because of the non-linear element that is somewhere in structure.  Current does flow in the reverse direction for erase.

PhyandEE
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Re: CBRAM? ECM or EM good question
PhyandEE   10/1/2013 11:50:12 PM
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I don't quite understand why they use Ag in a circuit. Silver is known for its serous migration effects under an electrical field. The heat by current makes this even worse. I don't know how they solve the reliablity issue using such a material.

Ron Neale
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Re: CBRAM? ECM or EM good question
Ron Neale   10/2/2013 5:26:27 AM
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PHYandEE: I think you will find I made the same point in my comment to Peter Clarke that you will find in the last page of his piece above. I think the fact that silver is a fast diffuser in silicon and needs very little encouragement (electric field, current, heat) to move is the very reason the Crossbar device "works".

However, remember there was a time, for similar resons, when if you suggested that you wanted to use copper as a conductor on silicon people would have advised you it was not a wise step, they might have used stronger language, now its use is common.

 

PhyandEE
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Re: CBRAM? ECM or EM good question
PhyandEE   10/2/2013 8:47:48 AM
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Copper might be a different story. To solve this problem, for example, additional diffusion barriers are used. 

But in their work, they seem to use silver as the conducting bridge (filament). The silver atoms diffuse through the amorphous silicon and form the filament for switching. The problem comes. Silver atoms can diffuse through the whole silicon layer. The silicon layer can not be perfect. With the electrical field applied, with the heat generated, and with the time, it is a big problem. 

Ron Neale
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Re: CBRAM? ECM or EM good question
Ron Neale   10/2/2013 9:52:03 AM
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PhyandEE: I was not trying to minimize the potential problems of mixing Ag and the silicon fab process but I think it should be possible to create an Ag based memory pore structure that keeps the silver isolated, in the same way as in the case of copper-silicon. However, I think the fact that silver is a fast diffuser in silicon raises a potential reliability problem at the memory cell level. The filament represents a silver concentration gradient in the a-Si so I would think there is a distinct possiblility that with the device in its on state the filament might just diffuse away in a radial direction with time-temperature, resulting in failure. If that is what you were trying to imply then I agree with you. When we see the reliability test results for representative devices (20nm) that should give us a good idea of the magnitude of the problem, "big" or otherwise.

 

yjdong
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Re: CBRAM? ECM or EM good question
yjdong   10/15/2013 4:07:03 PM
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The reason Ag was selected is: it is the only metal that showed rectified switching behavior in the metal/a-Si/c-Si structures that I tried.

The origin of crossbar switch can be tracked back to this paper.

http://cmliris.harvard.edu/assets/NanoLett_8_386.pdf

Besides the fast diffusion issue as you discussed, the poor thermal and chemical stability of Ag could also be problems when scaling down and stacking up 3D crossbar arrays.

I thought some Ag based alloys (with better stability) could be one way to overcome these problems while maintaining the rectified switching performance.

Hope Crossbar could give them a try.

 

Ron Neale
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Re: CBRAM? ECM or EM good question
Ron Neale   10/15/2013 6:36:40 PM
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yjdong: Yes other fast diffusing elements or alloys may be possible and certainly should be tried (Cu or as you suggest an alloy, e.g. CuAg ?). For the paper I was preparing I was going to suggest three locations for the diode or non-lnear element. The first choice is the contact between the tip of the silver column and the poly silicon, forming a Shottky. If in that case the actual growth and removal of the bridge occurs at its centre away from both electrodes, it would mean the the diode and the contact between the silver and the column remain fixed once "formed" If a diode in that location must be formed and remade for each write/erase event that adds another variable to my concerns about the contact between the Ag electrode and the silver column or dendrites

If you are prepared to accept that the bridge leaves a small tunneling gap at its tip and then I suppose there is just the possibility that a diode could be formed  between all the interfaces between the Ag and the polysilicon or at the polySi-to-aSi interface.  I think the diagram the accompanies this article does not attempt to account from where the ions shown floating in the a-Si have come.  If you contact me through EETimes your certainly welcome to my diagrams/figures. Is silver essential don't know.

PhyandEE
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Re: CBRAM? ECM or EM good question
PhyandEE   10/16/2013 11:56:48 PM
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Do you think what is the difference between your work at Harvard and the work at U Michigan?

 

PhyandEE
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Re: CBRAM? ECM or EM good question
PhyandEE   10/17/2013 12:13:26 AM
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-yjdong-

You said you tried other metals. Why they did not work? Is it because they do not have a good diffusion capability as silver?

yjdong
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Re: CBRAM? ECM or EM good question
yjdong   10/22/2013 10:07:38 PM
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To Ron Neale,

I agree that the most possible choice of the non-linear element location is the contact between silver filament tip and the polysilicon, but not sure whether it is a Shottky or not.

Just for your information, a good theory has to be able to explain the observed metal differences.

Some examples of other metal/a-Si/c-Si switching behavior can be found in fig12 of patent publication #:US20110001117 A1
http://www.google.com/patents/US20110001117?cl=en

Metal dependence was also observed in previous work on metal/a-Si/metal switches (like summarized in this reference: Owen, A. E. et al. Int. J. Electron. 1992, 73, 897.)
It was this paper, also your classical 1970 paper, that made me realize the origin of the switching could be the amorphous semiconductor and motivated me to try different metals, which led to the discovery of the Ag/a-Si/c-Si switch in Nanowires.

To RhyandEE,

The work at Harvard was based on bottom up nanowires, while UMichigan work by my previous colleague was to apply this discovery to CMOS compatible planar structures, which wasn't of interest to my advisor at that time.

As to why other metals didn't work as well, the diffusivity difference could be one reason. HRTEM observation of the switching process might provide the ultimate experimental explanations of the metal difference. Which I believe Umich are still working on. But there might be some technical difficulty in observing Ag/a-Si/c-Si structures in TEM and the video they presented on Crossbar website may not be clear enough yet. 

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